Diazido{(S)-1-phenyl-N,N-bis[(2-pyridyl)methyl]ethanamine}copper(II)
نویسندگان
چکیده
In the title compound, [Cu(N(3))(2)(C(20)H(21)N(3))], the Cu(II) ion is coordinated by the three N atoms of the (S)-1-phenyl-N,N-bis-[(2-pyrid-yl)meth-yl]ethanamine ligand and two N atoms from two azide anions, resulting in a distorted square-pyramidal environment. A weak inter-molecular C-H⋯N hydrogen-bonding inter-action between one pyridine group of the ligand and an azide N atom of an adjacent complex unit gives a one-dimensional chain structure parallel to the c axis.
منابع مشابه
Crystal structure of {(S)-1-phenyl-N,N-bis[(pyridin-2-yl)methyl]ethanamine-κ3 N,N′,N′′}bis(thiocyanato-κN)zinc from synchrotron data
The title ZnII complex, [Zn(NCS)2(C20H21N3)], has been characterized by synchrotron single-crystal diffraction and FT-IR spectroscopy. The central ZnII ion has a distorted square-pyramidal coordination geometry, with three N atoms of the chiral (S) 1-phenyl-N,N-bis-[(pyridin-2-yl)meth-yl]ethanamine (S-ppme) ligand and one N atom of a thio-cyanate anion in the equatorial plane, and one N atom of...
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عنوان ژورنال:
دوره 67 شماره
صفحات -
تاریخ انتشار 2011